You can get Intellisense from XSD with Visual Studio 2005, it really great. Check out this example.
<?xml version="1.0"?>
<ImportSession xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
xsi:noNamespaceSchemaLocation="acap.xsd">
<Batches>
<Batch BatchClassName="Client" RelativeImageFilePath="Images" EnableAutomaticSeparationAndFormID="1">
<Pages>
<Page ImportFileName="test.pdf"/>
</Pages>
</Batch>
</Batches>
</ImportSession>